The conformational locking of asparagine.

نویسندگان

  • Carlos Cabezas
  • Marcelino Varela
  • Isabel Peña
  • Santiago Mata
  • Juan C López
  • José L Alonso
چکیده

One dominant structure has been identified analysing the rotational spectrum of asparagine in sharp contrast with the multiconformational behaviour for other amino acids with polar side chains. This locking of the conformational variety to a single conformer has been ascribed to an intramolecular hydrogen bonding network involving α-amine, α-carboxylic and amide groups.

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عنوان ژورنال:
  • Chemical communications

دوره 48 47  شماره 

صفحات  -

تاریخ انتشار 2012